What is the most efficient medium for solar water heating? Can
oils be used in solar heating systems?
Water is the most efficient
liquid for transferring heat from one place to another such as in a
solar hot water system. Water has a specific heat of 1 btu/lb °F
Specific
heat or thermal capacity can be thought of as the ability of a
substance to absorb or maintain heat.
A
solar hot water system is most efficient when the heat transfer
medium is 100% water. However, in most of the country this isn't
possible because of the possibility of freezing. Typically we add
propylene glycol to water so that it won't freeze. Propylene glycol
has a specific heat of .60 btu/lb °F.
So
when we add glycol to the system's water we lower the efficiency of
the system. The specific heat of a 50/50 mixture of glycol and water
is .85 btu/lb at 80°F.
So it holds 15% less heat than pure water. So we would need 15% more
storage capacity to store the same amount of heat than if we were
using 100% water as our heat transfer medium.
Oils
have specific heat ratios in the neighborhood of .40 - .50 btu/lb °F.
Oil actually helps engines run cooler. They are not very efficient
at retaining heat. They are also very viscous which makes them harder
to pump, which uses more energy. They would not make a good fit for
solar heating.
The
only other liquid that has a higher specific heat than water is
ammonia. Ammonia however, wouldn't make a good solar heat transfer
fluid since it boils at -27°F.
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